Organic Chemistry I

Aromatic Nomenclature


Common Names

Since aromatic compounds have been known since antiquity, many of these compounds have common names. The common names for several important aromatic compounds are listed below:

Common names for some aromatic compounds

Mono-Substituted Benzene Derivatives

If the substituent contains six carbons or fewer, then the compound is named as a substituted benzene compound.

Examples:
Systematic names for mono-substituted aromatic compounds

If the substituent contains seven or more carbons, then the compound is named as a phenyl- or benzyl- substituted alkane:

Phenyl and benzyl groups

Examples:
Phenyl- and benzyl- substituted alkanes

Di-Substituted Benzene Derivatives

Di-substituted benzene derivatives are named using the ortho, meta, and para conventions:

Ortho, meta, and para substitution patterns

Examples:
Di-substituted aromatic compounds

Poly-Substituted Benzene Derivatives

Benzene derivatives with more than two substituents are named by numbering the position of each substituent. List the substituents alphabetically, with the numbers having the lowest possible sum.

Examples:
Systematic names for poly-substituted aromatic compounds