=C-H |
Stretch for sp2 C-H occurs at values between 3100-3010 cm-1. |
=C-H |
Out-of-plane (oop) bending occurs in the range 1000-650 cm-1. |
C=C |
Stretch occurs at 1660-1600 cm-1; often conjugation moves C=C stretch to lower frequencies and increases the intensity. Symmetrically substituted bonds (e.g., 2,3-dimethyl-2-butene) do not absorb in the infrared (no dipole change). Symmetrically disubstituted (trans) double bonds are often vanishingly weak in absorption; cis are stronger. |

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